1. No category

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ODDELEK 1: Identifikacija snovi/zmesi in družbe/podjetja
1.1 Dentifikator izdelka
Komercialno ime:
REACH registrirna št.:
Nafta
01-2119475133-43-XXXX
št.
št.
št.
št.
št.
37
38
39
41
42
-
Lahki bencin LSR (RB)
Lahki bencin (BK)
Nafta (RB)
Virgin Nafta (RB)
Virgin Nafta (BK)
1.2 Pomembne identificirane uporabe snovi ali zmesi in odsvetovane uporabe
Splošna uporaba
Snov za uporabo v petrokemiji
Identificirane uporabe
1. Proizvodnja snovi
1a. Porazdelitev snovi
1b. Uporaba kot vmesni produkt
2. Priprava in (pre-)pakiranje snovi in zmesi
3a. Uporaba pri premazih
4a. Uporaba v čistilnih sredstvih
12a. Uporaba kot gorivo: Industrijsko
12b. Uporaba kot gorivo: Obrt
12c. Uporaba kot gorivo: Porabnik
13. Proizvodnja in predelava gume: Industrijsko
1.3 Podrobnosti o dobavitelju varnostnega lista
Naziv firme:
Eni Deutschland GmbH
23
Cesta/poštni predal:
Sonnenstr.
Država, poštna št., kraj:
Telefon:
Telefaks:
D-80331 Muenchen
+49 (0)89-59 07-0
+49 (0)89-59 63-03
območje za informiranje:
Herr Hückinghaus,
Telefon: +49 (0)89-59 07-344, Email: ulrich.hueckinghaus@agip.de
1.4 Telefonska številka za nujne primere
Beratungsstelle für Vergiftungserscheinungen (GIZ)
Telefon: +49 (0)228-19240
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ODDELEK 2: Določitev nevarnosti
2.1 Razvrstitev snovi ali zmesi
Klasifikacija (CLP):
STOT SE. 3; H336
Repr. 2; H361
Lahko povzroči zaspanost ali omotico.
Verjetno lahko negativno vpliva na plodnost ali poškoduje otroka v
materinem telesu.
Aquatic Chronic 2; H411 Strupeno za vodne organizme, z dolgotrajnimi učinki.
Asp. Tox. 1; H304
Pri zaužitju in vstopu v dihalne poti je lahko smrtno.
Skin Irrit. 2; H315
Povzroča draženje kože.
Flam. Liq. 2; H225
Lahko vnetljiva tekočina in hlapi.
Carc. 1B; H350
Lahko povzroči raka.
Muta. 1B; H340
Lahko povzroči genetske okvare.
Klasifikacija glede na Direktivo 67/548/EGS:
Carc. Cat. 2; R45 Lahko povzroči raka.
Muta. Cat. 2; R46 Lahko povzroči dedne genetske okvare.
F; R11
Lahko vnetljivo.
Xn; R65
Zdravju škodljivo: pri zaužitju lahko povzroči poškodbo pljuč.
Xi; R38
Draži kožo.
R67
Hlapi lahko povzročijo zaspanost in omotico.
N; R51-53
Strupeno za vodne organizme: lahko povzroči dolgotrajne škodljive učinke
na vodno okolje.
2.2 Elementi etikete
Oznaka (CLP)
Opozorilna beseda
Stavki o nevarnosti
Nevarno
H225
H304
H315
H336
H340
H350
H361
H411
Varnostna navodila
P201
P210
P280
Lahko vnetljiva tekočina in hlapi.
Pri zaužitju in vstopu v dihalne poti je lahko smrtno.
Povzroča draženje kože.
Lahko povzroči zaspanost ali omotico.
Lahko povzroči genetske okvare.
Lahko povzroči raka.
Verjetno lahko negativno vpliva na plodnost ali poškoduje otroka
v materinem telesu.
Strupeno za vodne organizme, z dolgotrajnimi učinki.
Pred uporabo pridobiti posebna navodila.
Hraniti ločeno od vročine/isker/odprtega ognja/vročih površin. —
Kajenje prepovedano.
Nositi zaščitne rokavice/zaščitno obleko/zaščito za oči/zaščito za
obraz.
P301+P310
PRI ZAUŽITJU: takoj pokličite CENTER ZA ZASTRUPITVE ali
zdravnika.
P403+P233
Hraniti na dobro prezračevanem mestu. Hraniti v tesno zaprti
posodi.
P501
Odstraniti vsebino/posodo nevarnih ali posebnih odpadkov.
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Oznaka (67/548/EES ali 1999/45/ES)
F
T
lahko vnetljivo
R-stavki:
R 45
R 46
R 11
R 38
R 51/53
R 65
R 67
S-stavki:
S 53
S2
S 23
S 24
S 29
S 36/37
S 43
S 45
S 51
S 61
S 62
Verzija 6 / Stran: 3 od 14
N
okolju nevarno
Lahko povzroči raka.
Lahko povzroči dedne genetske okvare.
Lahko vnetljivo.
Draži kožo.
Strupeno za vodne organizme: lahko povzroči dolgotrajne
škodljive učinke na vodno okolje.
Zdravju škodljivo: pri zaužitju lahko povzroči poškodbo pljuč.
Hlapi lahko povzročijo zaspanost in omotico.
Izogibati se izpostavljanju - pred uporabo pridobiti posebna
navodila.
Hraniti izven dosega otrok.
Ne vdihavati hlapov.
Preprečiti stik s kožo.
Ne izprazniti v kanalizacijo.
Nositi primerno zaščitno obleko in zaščitne rokavice.
Za gašenje uporabiti Pena, sredstvo za suho gašenje, vodni curek
ali ogljikov dioksid.
Ob nezgodi ali slabem počutju, takoj poiskati zdravniško pomoč.
Uporabljati le v dobro prezračevanih prostorih.
Ne izpuščati/odlagati v okolje. Upoštevati posebna
navodila/varnostni list.
Po zaužitju ne izzivati bruhanja: takoj poiskati zdravniško pomoč
in pokazati embalažo ali etiketo.
2.3 Druge nevarnosti
Hlapi so težji od zraka, širijo se po tleh.
Tudi pri nizkih okoljskih temperaturah lahko nastajajo eksplozivne zmesi
hlapov/zraka.
ODDELEK 3: Sestava/podatki o sestavinah
3.1 Snovi
Kemična karakterizacija (snov):
Nafta z nizkim vreliščem
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UVCB snov - Podatki o sestavinah:
Sestavina
EINECS 265-065-1
CAS 64741-63-5
REACH
01-2119474679-18-xxxx
EINECS 265-042-6
CAS 64741-42-0
EINECS 265-151-9
CAS 64742-49-0
EINECS 265-046-8
CAS 64741-46-4
EINECS 265-041-0
CAS 64741-41-9
EINECS 270-690-8
CAS 68476-50-6
REACH
01-2119447106-44-xxxx
EINECS 200-753-7
CAS 71-43-2
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Oznaka
Nafta
(zemeljsko
olje), lahka
katalitsko
reformirana
Nafta
(zemeljsko
olje), v
velikem
temperaturnem
intervalu,
direktna
destilacija
Nafta
(zemeljsko
olje), lahka,
obdelana z
vodikom
Nafta
(zemeljsko
olje), lahka iz
direktne
destilacije
Nafta
(zemeljsko
olje), tezka iz
direktne
destilacije
Ogljikovodiki,
C >=5,
pretezno
C.sb.5-6
Vsebnost
0-100 %
Benzen
>=
0,1 %
0-100 %
0-100 %
0-100 %
0-100 %
0-100 %
Klasifikacija
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 2; R45.
Muta. Cat. 2; R46. Xn; R65.
CLP: Muta. 1B; H340.
Carc. 1B; H350.
Asp. Tox. 1; H304.
EU: Carc. Cat. 1; R45.
F; R11. Muta. Cat. 2; R46.
Xn; R65. T; R48/23/24/25.
Xi; R36/38.
CLP: Asp. Tox. 1; H304.
Carc. 1A; H350.
Eye Irrit. 2; H319.
Flam. Liq. 2; H225.
Muta. 1B; H340.
STOT RE 1; H372.
Skin Irrit. 2; H315.
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Dodatna opozorila:
Verzija 6 / Stran: 5 od 14
Verjetno lahko negativno vpliva na plodnost ali poškoduje otroka v materinem
telesu. test
CAS 64741-63-5 - Chemiebenzin:
Zmes ogljikovodikov, C5-C11, območje vrenja 35°C do 190°C
CAS 64741-42-0 - Full Range Naphtha:
Zmes ogljikovodikov, C4-C11, območje vrenja-20°C do 220°C
CAS 64742-49-0 - Light Distillate Feedstock:
Zmes ogljikovodikov, C4-C11, območje vrenja-20°C do 190°C
CAS 64741-46-4-5 - Light Virgin Naphtha:
Zmes ogljikovodikov, C4-C10, območje vrenja-20°C do 180°C
CAS 64741-41-9 - Mittelbenzin:
Zmes ogljikovodikov, C6-C12, območje vrenja 65°C do 230°C
CAS 68476-50-6 - Leichtbenzin:
Zmes ogljikovodikov, >= C5
ODDELEK 4: Ukrepi za prvo pomoč
4.1 Opis ukrepov za prvo pomoč
splošna navodila:
Po vdihavanju:
Po stiku s kožo:
Po stiku z očmi:
Po zaužitju:
Oseba, ki nudi prvo pomoč: Paziti na samozaščito!
vdihavanje večjih količin povzroča: Motnje v koordinaciji, opitost, glavobol,
draženje na bruhanje.
Pri dolgotrajnejši izpostavljenosti: vrtoglavica, nezavest in zastoj dihanja
možno.
Prizadete odvesti na sveži zrak.
V primeru težav z dihanjem dati kisik. Pri nepravilnem dihanju ali prenehanju
dihanja dati umetno dihanje. Takoj poiskati zdravniško pomoč.
V primeru nevarnosti, da oseba izgubi zavest, jo poležemo in transportiramo
v stabilnem bočnem položaju.
Takoj sleči vso onesnaženo obleko.
Ob stiku s kožo takoj sprati z veliko vode in mila. V primeru dražanja kože
obiskati zdravnika.
Z odprtimi vekami takoj spirati 10 do 5 minut s tekočo vodo. Zatem se
posvetovati z očesnim zdravnikom.
Ne povzročati bruhanja. Če je oseba pogoltnila proizvod oz. če bljuva, je
nevarnost za vdor v pljuča. V primeru bruhanja in nezavesti stavilan stranska
lega. Dihalne poti pustiti proste. Takoj poiskati zdravniško pomoč.
4.2 Najpomembnejši simptomi in učinki, akutni in zapozneli
Po vdihavanju:
Glavobol, vinjenost, slabost, omotičnost, vrtoglavica, težko dihanje.
V primeru prisotnosti večjih koncentracij: Motnje CNS, nezavest, narkoza,
zastoj dihanja.
Po použitju: Motnje prebavnega trakta, driska.
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4.3 Navedba kakršne koli takojšnje medicinske oskrbe in posebnega
zdravljenja
Lahko se pokažejo naslednji simptomi: Glavobol, vinjenost, slabost, draženje
na bruhanje, omotičnost, vrtoglavica, težko dihanje, nezavest, zastoj dihanja.
V primeru zaužitja in zatem bruhanja lahko pride do aspiracije v pljuča, kar
povzroči kemijsko pneumonijo ali zadušitev.
Zdravljenje:
Po potrebi dajanje kisika.
V primeru nadraženja pljuč prvo zdravljenje s spray-em Dexametazon.
ODDELEK 5: Protipožarni ukrepi
5.1 Sredstva za gašenje
primerna sredstva za gašenje:
Pena, sredstvo za suho gašenje (ABC-prah), vodni curek, ogljikov dioksid.
iz varnostnih razlogov neprimerna sredstva za gašenje:
Močni vodni curek
5.2 Posebne nevarnosti v zvezi s snovjo ali zmesjo
Lahko vnetljivo.
Možnost nastajanja eksplozivnih zmesi hlapov in zraka. Paziti na povratni
vžig.
V primeru požara lahko nastane: Dušikovi oksidi (NOx), žveplovi oksidi,
ogljikov monoksid in ogljikov dioksid.
5.3 Nasvet za gasilce
posebna zaščitna oprema pri gašenju požara:
Dodatna navodila:
Uporabiti zaščitni dihalni aparat, ki ni odvisen od zraka v okolju, in nositi
zaščitno oblačilo za kemikalije.
Ogrožene rezervoarje ohladiti z razprševanjem vode. Ne vdihavati plinov, ki
nastanejo ob požaru in/ali eksploziji.
Kontaminirano sredstvo za gašenje zbirati ločeno. Preprečiti prodiranje vode
za gašenje v vodotoke ali podtalnico.
ODDELEK 6: Ukrepi ob nenamernih izpustih
6.1 Osebni varnostni ukrepi, zašcitna oprema in postopki v sili
Preprečiti stik s substanco. Nositi primerno zaščitno obleko.
Ljudi spraviti na varno. Onemogočiti dostop nezaščitenim osebam.
Skrbeti za zadostno prezračevanje. Ne vdihavati hlapov.
6.2 Okoljevarstveni ukrepi
Preprečiti širjenje po površini (npr.z zajezitvijo ali oljnimi barierami).
Preprečiti prodiranje v zemljo, vodotoke ali kanalizacijo. Nevarnost
eksplozije! V primeru izločanja obvestiti pristojne organe.
6.3 Metode in materiali za zadrževanje in čiščenje
Odstraniti z vodne gladine (npr. posneti, izsesati).
Pobrati z negorljivim sredstvom ki veže tekočine (npr.
pesek/zemlja/kremenova prst/Vermiculit) in skladno s predpisi odstraniti.
Ne odplakovati z vodo ali vodenimi čistilnimi sredstvi.
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Dodatna navodila:
Verzija 6 / Stran: 7 od 14
Odstraniti vse vžigalne pobude. Paziti na povratni vžig. Uporabljati orodje, ki
ne iskri.
Posebna nevarnost za spolzkost zaradi izteklega/ politega proizvoda.
6.4 Sklicevanje na druge oddelke
ni potrebno
ODDELEK 7: Ravnanje in skladiščenje
7.1 Varnostni ukrepi za varno ravnanje
Navodila za varno uporabo
Skrbeti za dobro odzračevanje in prezračevanje skladišča in delovnega
mesta.
Pri rokovanju je potrebno preprečiti brizganje in razlitje.
preprečite nastajanje aerosola in megle. Ne vdihavati hlapov.
Med uporabo ne jesti, ne piti in ne kaditi. Uporabiti samo za čiščenje.
Navodila za zaščito pred požarom in eksplozijo:
Hraniti ločeno od virov vžiga - ne kaditi. Preprečiti statično naelektrenje.
Predvideti ozemljitev posod, apartur, črpalk in naprav za izsesavanje.
Uporabljati samo orodje, ki je antistatično (ki ne iskri). Uporabljeti je
potrebno antistatično oblačilo.
7.2 Pogoji za varno skladiščenje, vključno z nezdružljivostjo
zahteve glede skladiščnih prostorov in posod:
Hraniti v tesno zaprti posodi ne dobro prezračevanem mestu.
Preprečiti stik z viri vžiga in toplote.
Primerni material: jeklo, avtorizirana rezervna ročka
Dostop do skladišča je dovoljen samo strokovnemu osebju.
Opozorila glede skupnega skladiščenju
Razred skladišča VCI:
Ne shranjevati skupaj z snovmi, ki pospešujejo gorenje, samovnetljivimi
snovmi kot tudi lahko vnetljivimi trdnimi snovmi.
3 = Vnetljive tekoče snovi
7.3 Posebne končne uporabe
Snov za uporabo v petrokemiji
ODDELEK 8: Nadzor izpostavljenosti/osebna zaščita
8.1 Parametri nadzora
Št.CAS
71-43-2
Dodatna navodila:
Oznaka
Benzen
Vrsta
Evropa, BOELV: TWA
Mejna vrednost
Koža 3,25 mg/m3; 1 ppm
mejna vrednost Otto goriva (Analogni zaključek): 250 mg/m3
(Mejna vrednost za Otto goriva po DIN EN 228 je mejna vrednost vsot vseh
ogljikovodikov vključno z benzolom in vsemi komponentami, ki vsebujejo
kisik.)
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DNEL Kratkotrajno, delavci, inhalacijski: 1300 mg/m3 / 15 (4320 mg/m3/h)
DNEL Kratkotrajno, delavci, inhalacijski: 1110 mg/m3 / 15 (2400 mg/m3/h)
DNEL Dolgotrajno, delavci, inhalacijski: 840 mg/m3 / 8h (10000 mg/m3/6 h)
DNEL Kratkotrajno, uporabniki, inhalacijski: 1200 mg/m3 / 15
(4320 mg/m3/h)
DNEL Kratkotrajno, uporabniki, inhalacijski: 640 mg/m3 / 15
(2400 mg/m3/h)
DNEL Dolgotrajno, uporabniki, inhalacijski: 180 mg/m3 / 8h (10000
mg/m3/6 h)
DNEL
8.2 Nadzor izpostavljenosti
Skrbeti za dobro prezračevanje prostora ter za odsesavanja/odzračevanje.
V delovnem okolju naj bosta lahko dostopna tuš in priprava za spiranje oči.
Z materialom se naj rokuje samo v zaprtih napravah ali sistemih.
Nadzor izpostavljenosti na delovnem mestu
zaščita dihal:
V primeru prisotnosti večjih koncentracij:
Dihalni aparat z/s filter A (označevalna barva rjavo) v skladu z/s EN 141.
(Hlapi do 0,1 Vol.-%: A1, do 0,5 Vol.-% A2, do 1 Vol.-% A3.)
Pri nejasnih razmerah in vsebnosti kisika pod 17% uporabiti zaščitno dihalno
napravo, ki ni odvisna od okoljskega zraka.
Kontrola zraka za dihanje: Testna cevka Auer Benzin A, BNZ, Gasolin 30, QL.
zaščita rok:
Nepropustne zaščitne rokavice v skladu z/s EN 374.
Material za rokavice: Nitrilni kavčuk.
neustrezni material: Usnje, tkanina.
Rok trajanja (maksimalni čas nošenja): > 480 min.
Upoštevati podatke proizvajalca zaščitnih rokavic glede prepustnosti in
trajnosti.
Zaščita oči:
Zaščitna očala, ki dobro tesnijo v skladu z/s EN 166.
Pri povečani ogroženosti dodatno Ščitnik za obraz
zaščita telesa:
Antistatična zaščitna obleka/škornji.
zaščitni in higienski ukrepi:
Na delovnem mestu je prepovedano jesti, piti, kaditi, njuhati.
Takoj sleči vso onesnaženo obleko.
Čistilne krpe, prepojene s proizvodom, ne nositi v žepu.
po opravljenem delu sta potrebna temeljito čiščenje in nega kože.
ODDELEK 9: Fizikalne in kemijske lastnosti
9.1 Podatki o osnovnih fizikalnih in kemijskih lastnostih
Oblika/ stanje:
Barva
Vonj:
Vrelišče/ območje vrenja:
Tališče/ talilno območje:
Plamtišče:
Temperatura vžiga
Samovnetljivost:
Meje eksplozivnosti:
Parni tlak:
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51 - 186 °C (DIN EN ISO3405)
<= -60 °C (Eaton 1990)
<0 do <55 Stopinj C (EN ISO 13736)
ca. 200 °C
280 - 470 °C (Eaton 1990)
SME (Spodnja meja eksplozivnosti): 0,60 Vol%
ZEM (zgornja eksplozivna meja): 9,50 Vol%
pri 38 °C: CONCAWE (2010) 40-2400 hPa (EN 13016-1)
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Razdelitveni koeficient n-oktanol/voda:
pri 15 °C: 0,7434 g/mL (ISO 3675/EN ISO 12185)
pri 20 °C: majhno
>= 3 log P(o/w)
Viskoznost, kinematski:
pri 20 °C: ca. 0,68 mm2/s
Gostota:
Vodotopnost:
Verzija 6 / Stran: 9 od 14
9.2 Druge informacije
Vsebnost žveplo (DIN 51400 T.6): max. 1500 mg/kg
ODDELEK 10: Obstojnost in reaktivnost
10.1 Reaktivnost
Lahko vnetljiva tekočina in hlapi.
10.2 Kemijska stabilnost
Proizvod je ob normalnih pogojih skladiščenja stabilen.
10.3 Možnost poteka nevarnih reakcij
Ni razpoložljivih podatkov
10.4 Pogoji, ki se jim je treba izogniti
Lahko vnetljivo. Preprečiti odprto svetlobo, ogenj in druge vire vžiga.
Pri močnem segretju: Nevarnost požara/Nevarnost za samovžig.
Možnost nastajanja eksplozivnih zmesi hlapov in zraka.
Hlapi so težji od zraka, širijo se po tleh.
10.5 Nezdružljivi materiali
oksidacijsko sredstvo
10.6 Nevarni razpadli proizvodi
V primeru požara lahko nastane: Dušikovi oksidi (NOx), žveplovi oksidi,
ogljikov monoksid in ogljikov dioksid.
ODDELEK 11: Toksikološki podatki
11.1 Podatki o toksikoloških učinkih
Akutna toksičnost:
LD50 Podgana, oralni:
> 5000 mg/[m3] (OECD TG 401)
LC50 Podgana, inhalacijski:
> 5,61 mg/L (OECD TG 403)
LD50 Zajec, kožni:
> 2000 mg/kg (OECD TG 402)
NOAEL Podgana, kožni:
3750 mg/kg/28d (OECD TG 410)
NOAEL Podgana, inhalacijski: 9840 mg/m3 (OECD TG 412)
Po vdihavanju:
Hlapi lahko povzročijo zaspanost in omotico.
Po zaužitju:
Zdravju škodljivo: pri zaužitju lahko povzroči poškodbo pljuč.
Po stiku s kožo:
Dražeč.
Nevarnost hudih okvar zdravja pri dolgotrajnejši izpostavljenosti.
Na kožo deluje razmaščujoče.
Po stiku z očmi:
Dolgotrajnejša in/ali ponavljajoča se izpostavljenost lahko povzroči
nadraženost oči.
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kancerogeni učinki, mutageni učinki kot tudi učinki, ki ogrožajo razmnoževanje
Repr. 2 - Verjetno lahko negativno vpliva na plodnost ali poškoduje otroka v
materinem telesu.
Carc. 1B - Lahko povzroči raka.
Muta. 1B - Lahko povzroči genetske okvare.
Simptomi
Po vdihavanju:
Glavobol, vinjenost, slabost, omotičnost, vrtoglavica, težko dihanje.
V primeru prisotnosti večjih koncentracij: Motnje CNS, nezavest, narkoza,
zastoj dihanja.
Po použitju: Motnje prebavnega trakta, driska.
splošne opombe
Oralno zaužitje oz. inhaliranje povzroči pri podganah nefrotoksične
spremembe. Strupen učinek na organe, ki proizvajajo kri.
Proizvod vsebuje benzol, ki povzroča levkemijo.
Mutagenost:
ni mutageno pri bakterijah, in-vitro (OECD TG 471 )
Genske mutacije celic sesalcev, in-vitro (OECD TG 476): negativen
Test mikro jeder in-vivo, Podgana (OECD TG 474): negativen
Kromosomske aberacije, in-vivo, Podgana (OECD 475): negativen
Karcinogenost:
Kronična (dolgotrajna), kožni aplikacija Miš, NOEL: 0,5 ml (blended
gasoline): no significantly changes compared to negative and historical
controls
Kronična inhalacijska toksičnost, Podgana, NOEL: 292 ppm. Pri poizkusih na
živalih so pri glodalcih pri visoki kronični inhalativni izpostavljenosti opazili
porast števila tumorjev na jetrih. Pomen teh rezultativ za človeka ni
pojasnjen.
Strupenost za razmnoževanje:
NOAEL >24700 mg/m3 (OECD TG 421). Ne vpliva na razmnoževalno
sposobnost pri poskusih z živalmi.
:
:
pri Koncentracija > 20000 mg/m3.
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ODDELEK 12: Ekološki podatki
12.1 Strupenost
toksičnost vode:
Strupeno za vodne organizme: lahko povzroči dolgotrajne škodljive učinke na
vodno okolje.
Akutni učinki:
Toksičnost za alge:
sladkovodne vrste: 72h EL50 pseudokirchnerialla subcapitata (zelene alge):
3,1 mg/L (OEDC 201, based on: ) (Izvor: CONCAWE 1995o)
sladkovodne vrste: 72h NOELR pseudokirchnerialla subcapitata (zelene alge):
0,5 mg/L (OEDC 201, based on: ) (Izvor: CONCAWE 1996a)
Toksičnost za ribe:
sladkovodne vrste: 96h LC50 (Postrv (Oncorhynchus mykiss)): 10 mg/L
(OEDC 203) (Izvor: CONCAWE 1995a, 1996a,b)
sladkovodne vrste: 96h LC50 (črnoglavi pisanec): 8,2 mg/L (EPA
66013-75-009) (Izvor: PPSC 1995a)
Strupenost za nevretenčarje:
sladkovodne vrste: 48h ES50 (daphnia magna (velika vodna bolha)): 4,5
mg/L (OEDC 202, based on: Mobilnost) (Izvor: CONCAWE 1995h, 1996j,k)
Bakteriološka toksičnost::
sladkovodne vrste Tetrahymena pyriformis: 72h LL50 15,41 mg/L (Metoda:
QSAR PETROTOX) (Izvor: Redman et al. 2010b)
Dolgoročni učinki:
sladkovodne vrste: Daphnia magna (velika vodna bolha): 21d NOEL: 2,6
mg/L (OEDC 211, based on: reprodukcija) (Izvor: Springborn Laboratories
Inc. 1999d)
Razred ogroženosti vode:
3 = Močno ogroža vodo
12.2. Obstojnost in razgradljivost
Druga navodila:
Inherentno biološko razgradljivo (Solano-Serena, F. et al (1999)).
(Neely, W.B., Blau, G.E. (1985))
12.3 Zmožnost kopičenja v organizmih
Razdelitveni koeficient n-oktanol/voda:
>= 3 log P(o/w)
12.4 Mobilnost v tleh
Razdelitev v okolju po model za preračune (PETRORISK):
zrak: 93,02 %
voda: 5,83 %
tla: 0,34 %
usedlina: 0,81 %
(Izvor: Redman et al., 2010a)
12.5 Rezultati ocene PBT in vPvB
ta snov ne izpolnjuje PBT-/vPvB-kriterijev odredbe REACH, aneks XIII.
12.6 Drugi neugodni učinki
splošna navodila:
Ne dopustiti, da pride v podtalnico, vodotoke ali kanalizacijo.
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ODDELEK 13: Odstranjevanje
13.1 Metode ravnanja z odpadki
Proizvod
Identifikacijska številka odpadka
priporočilo:
13 07 02* =
Odpadki pri tekočih gorivih: Bencin
* = odstranjevanje odpadnih snovi mora biti dokazljivo.
Predaja pooblaščenemu podjetju za odstranjevanje odpadnih snovi.
Možne alternative: Zažigati samo z uradnim dovoljenjem.
nadaljnji podatki
Prevoz s cisterno (cestni promet). Previdno in po možnosti popolnoma
izprazniti.
Previdnost pri izpraznjenih posodah. V primeru vžiga je možna eksplozija.
Preprečiti je treba vnašanje v okolje.
ODDELEK 14: Podatki o prevozu
14.1 Številka ZN
ADR/RID, IMDG, IATA:
1268
14.2 Pravilno odpremno ime ZN
ADR/RID:
IMDG, IATA:
NAFTNI DESTILATI, N.O.S.
PETROLEUM DISTILLATES, N.O.S.
14.3 Razredi nevarnosti prevoza
ADR/RID:
IMDG:
IATA:
razred 3, Koda: F1
Class 3, Code Class 3
14.4 Skupina embalaže
ADR/RID, IMDG, IATA:
I
14.5 Nevarnosti za okolje
Marine Pollutant
Yes
14.6 Posebni previdnostni ukrepi za uporabnika
Transport po kopnem (ADR/RID)
Opozorilna tabla:
ADR/RID: Številka nevarnosti 33, Številka ZN 1268
Nalepka z oznako nevarnosti
3
Omejene količine
500 mL
EQ
E3
Embalaža: Navodila
P001
Posebni predpisi za pakiranje
MP7 MP17
Prenosni rezervoarji: Navodila
T11
Prenosni rezervoarji: Posebni predpisi
TP1 TP8
Kodiranje rezervoarja
L4BN
Koda za omejitve predorov:
D/E
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ladijski transport (IMDG)
EmS:
Posebni predpisi
Omejene količine
EQ
Embalaža: Navodila
Embalaža: Predpisi
IBC: Navodila
IBC: Predpisi
Navodila za rezervoar: IMO
Navodila za rezervoar: UN
Navodila za rezervoar Predpisi
Stowage and segregation
Properties and observations
F-E, S-E
500 mL
E3
P001
T11
TP1, TP8
Category E.
Immiscible with water.
Zračni transport (IATA)
Flamm. liquid
E3
Forbidden
Pack.Instr. 351 - Max.Qty. 1 L
Pack.Instr. 361 - Max.Qty. 30 L
A3
3H
Hazard
EQ
Passenger Ltd.Qty.:
Passenger:
Cargo:
Special Provisioning
ERG
14.7 Prevoz v razsutem stanju v skladu s Prilogo II k MARPOL 73/78 in
Kodeksom IBC
Ni razpoložljivih podatkov
ODDELEK 15: Zakonsko predpisani podatki
15.1 Predpisi/zakonodaja o zdravju, varnosti in okolju, specifični za snov ali
zmes
Nacionalni predpisi - Nemčija
Razred skladišča VCI: 3 = Vnetljive tekoče snovi
Razred ogroženosti vode:
3 = Močno ogroža vodo
odredba v primeru motnje:
priloga I, Seznam snovi Nr. 8
Navodila za omejitev dela:
Pri delu upoštevati omejitve za mladostnike.
Pri delu upoštevati omejitve za nosečnice in doječe matere.
drugi predpisi, omejitve in odredbe:
Uporabiti samo za čiščenje.
Nacionalni predpisi - Švica
Vsebnost hlapljivih organskih spojin (VOC):
743 g/L
Nacionalni predpisi - Velika Britanija
koda DG-EA (Hazchem):
3YE
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Nacionalni predpisi - Države članice ES
Vsebnost hlapljivih organskih spojin (VOC):
100 % teže
Nacionalni predpisi - ZDA
Sistemi za ocenjevanje nevarnosti
4
3
0
NFPA Hazard Rating:
Health: 3 (Serious)
Fire: 4 (Severe)
Reactivity: 0 (Minimal)
HMIS Version III Rating:
Health: 3 (Serious) - Chronic effects
Flammability: 4 (Severe)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
HEALTH
*
FLAMMABILITY
PHYSICAL HAZARD
3
4
0
X
15.2 Ocena kemijske varnosti
Izveden je bil test glede varnosti za to snov.
ODDELEK 16: Drugi podatki
nadaljnje informacije
vzrok za zadnje spremembe:
Literatura:
Sprememba v odlomku 1: Številka za klic v sili
CONCAWE (Madouplein 1, B-1030 Brussels, Belgium):
- CSR Low Boiling Point Naphthas (Gasoline) 06/2010
- Dossier 'Liquified Petroleum Gas', 92/102
- Report 01/54 (Environmental Classification of Petroleum Substances Summary data and Rationale)
- Report 01/53 (Classification and of Labelling of Petroleum Substances
Directive)
- CONCAWE Dossier 'Liquified Petroleum Gas', 92/102 (Madouplein 1,
B-1030 Brussels, Belgium)
- CONCAWE Report 01/54 (Environmental Classification of Petroleum
Substances - Summary data and Rationale)
- CONCAWE Report 01/53 (Classification and of Labelling of Petroleum
Substances Directive)
Področje, na katerem je bil izdan sesznam podatkov
Kontaktna oseba:
glej poglavje 1, področje za informacije.
Podatki na tem listu so zbrani po najboljšem znanju in ustrezajo stanju podatkov na dan
obdelave. Vendar se pravno ne zavezujejo, da bodo upoštevali določene lastnosti.
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Anhang
Section 1 Exposure Scenario Title
Title:
Manufacture of substance
Use Descriptor
Sector(s) of Use
Process Categories
SU3, SU8, SU9
PROC1, PROC15, PROC2, PROC3, PROC8a,
PROC8b
ERC1, ERC4
ESVOC 1.1.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Manufacture of the substance or use as an intermediate, process chemical or extracting agent. Includes recycling/ recovery, material transfers, storage, maintenance and loading (ncluding marine vessel/barge,
road/rail car and bulk container).
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC1
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC1
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
General exposures (closed systems) PROC1
Handle substance within a closed system.
General exposures (closed systems) PROC2
Wear suitable gloves tested to EN374.
Sample via a closed loop or other system to avoid exposure.
Handle substance within a closed system.
General exposures (closed systems) PROC3
Seite 1 von 21
Ensure operation is undertaken outdoors.
Handle substance within a closed system.
Laboratory activities PROC15
Handle in a fume cupboard or under extract ventilation.
Bulk transfers (closed systems) PROC8b
Ensure material transfers are under containment or extract ventilation.
Equipment cleaning and maintenance PROC8a
Drain down and flush system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
Ensure operation is undertaken outdoors.
Store substance within a closed system.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 600000 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.03
Maximum daily site tonnage (kg/d): 2000000 kg / day
Regional use tonnage (tonnes/year): 18700000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.05
Release fraction to soil from process (regional only): 0.0001
Release fraction to wastewater from process: 0.003
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 80.4 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 99 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: 95.2 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Prevent discharge of undissolved substance to or recover from wastewater.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 10000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is:
2000000 kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
99.1 %
Seite 2 von 21
Conditions and measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated [ETW4]
Conditions and measures related to external recovery of waste
During manufacturing no waste of the substance is generated [ERW2]
Seite 3 von 21
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Section 1 Exposure Scenario Title
Title:
Distribution of substance
Use Descriptor
Sector(s) of Use
Process Categories
SU3, SU8, SU9
PROC1, PROC15, PROC2, PROC3, PROC8a,
PROC8b
ERC1, ERC2
ESVOC 1.1b.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and
small packs) of substance, including its sampling, storage, unloading, distribution and associated laboratory
activities.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Assumes use at not more than 20°C above ambient tem perature[G15]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC1
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC1
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
Seite 4 von 21
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
General exposures (closed systems) PROC1
Handle substance within a closed system.
Process sampling PROC3
Sample via a closed loop or other system to avoid exposure.
Laboratory activities PROC15
Handle in a fume cupboard or under extract ventilation.
Bulk transfers (closed systems) PROC8b
Ensure material transfers are under containment or extract ventilation.
Bulk transfers (open systems) PROC8b
Ensure material transfers are under containment or extract ventilation.
Equipment cleaning and maintenance PROC8a
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Drain down and flush system prior to equipment break-in or maintenance.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
Ensure operation is undertaken outdoors.
Store substance within a closed system.
General exposures (closed systems) with sample collection PROC2
Wear suitable gloves tested to EN374.
Handle substance within a closed system.
Sample via a closed loop or other system to avoid exposure.
General exposures (closed systems) Outdoor. PROC3
Handle substance within a closed system.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 37500 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.002
Maximum daily site tonnage (kg/d): 120000 kg / day
Regional use tonnage (tonnes/year): 18700000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.001
Release fraction to soil from process (regional only): 1e-005
Release fraction to wastewater from process: 1e-005
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 90 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
Seite 5 von 21
efficiency of =: >= 12 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is:
1100000 kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
95.5 %
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations
[ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations
[ERW1]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Seite 6 von 21
Section 1 Exposure Scenario Title
Title:
Formulation and (re)packing of substances and mixtures
Use Descriptor
Sector(s) of Use
Process Categories
SU10
PROC1, PROC15, PROC2, PROC3, PROC8a,
PROC8b
ERC2
ESVOC 2.2.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations,
including storage, materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and
small scale packing, sampling, maintenanance and associated laboratory activities.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Assumes use at not more than 20°C above ambient tem perature[G15]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC1
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC1
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
General exposures (closed systems) PROC1
Handle substance within a closed system.
General exposures (closed systems) PROC2
Wear suitable gloves tested to EN374.
Handle substance within a closed system.
Sample via a closed loop or other system to avoid exposure.
General exposures (closed systems) PROC3
Handle substance within a closed system.
Process sampling PROC3
Sample via a closed loop or other system to avoid exposure.
Laboratory activities PROC15
Handle in a fume cupboard or under extract ventilation.
Bulk transfers PROC8b
Seite 7 von 21
Ensure material transfers are under containment or extract ventilation.
Drum/batch transfers PROC8b
Ensure material transfers are under containment or extract ventilation.
Equipment cleaning and maintenance PROC8a
Drain down and flush system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
Wear suitable gloves tested to EN374.
Store substance within a closed system.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 30000 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.0018
Maximum daily site tonnage (kg/d): 100000 kg / day
Regional use tonnage (tonnes/year): 16500000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.025
Release fraction to soil from process (regional only): 0.0001
Release fraction to wastewater from process: 0.002
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 56.5 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: 94.7 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Prevent discharge of undissolved substance to or recover from wastewater.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 100000
kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
95.5 %
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations
Seite 8 von 21
[ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations
[ERW1]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Section 1 Exposure Scenario Title
Title:
Use in Coatings - Industrial
Use Descriptor
Sector(s) of Use
Process Categories
SU3
PROC1, PROC15, PROC2, PROC3, PROC8a,
PROC8b
ERC4
ESVOC 4.3a.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials
receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip,
flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Assumes use at not more than 20°C above ambient tem perature[G15]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC2
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC2
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
Seite 9 von 21
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
Film formation - force drying (50-100°C). stoving (>100°C). UV/EB radiation curing PROC2
Provide extract ventilation to points where emissions occur.
General exposures (closed systems) PROC3
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Handle substance within a closed system.
Material transfers PROC8b
Ensure material transfers are under containment or extract ventilation.
Laboratory activities PROC15
Handle in a fume cupboard or under extract ventilation.
Equipment cleaning and maintenance PROC8a
Drain down and flush system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC1
Store substance within a closed system.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 6200 tons/yr
Continuous release.
Emission Days (days/year): 300
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 1
Maximum daily site tonnage (kg/d): 21000 kg / day
Regional use tonnage (tonnes/year): 6200 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.98
Release fraction to soil from process (regional only): 0
Release fraction to wastewater from process: 0.007
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 94.1 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: 92.6 %
Organisation measures to prevent/limit release from site
Seite 10 von 21
Do not apply industrial sludge to natural soils.
Prevent discharge of undissolved substance to or recover from wastewater.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 21000
kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
95.5 %
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations
[ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations
[ERW1]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Section 1 Exposure Scenario Title
Title:
Use as a fuel - Industrial
Use Descriptor
Sector(s) of Use
Process Categories
SU3
PROC1, PROC16, PROC2, PROC3, PROC8a,
PROC8b
ERC7, ERC8B
ESVOC 7.12a.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment
maintenance and handling of waste.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Seite 11 von 21
Assumes use at not more than 20°C above ambient tem perature[G15]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC8b
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC8b
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
Bulk transfers (closed systems) PROC8b
Ensure material transfers are under containment or extract ventilation.
Drum/batch transfers PROC8b
Ensure material transfers are under containment or extract ventilation.
General exposures (closed systems) Use in contained batch processes Outdoor. PROC3
Handle substance within a closed system.
General exposures (closed systems) PROC1
Handle substance within a closed system.
General exposures (closed systems) PROC2
Wear suitable gloves tested to EN374.
Handle substance within a closed system.
Equipment cleaning and maintenance PROC8a
Drain down system prior to equipment break-in or maintenance.
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Store substance within a closed system.
Use as a fuel (closed systems) PROC16
Handle substance within a closed system.
refuelling PROC8b
Ensure material transfers are under containment or extract ventilation.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 1400000 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 1
Maximum daily site tonnage (kg/d): 4600000 kg / day
Seite 12 von 21
Regional use tonnage (tonnes/year): 1400000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.0025
Release fraction to soil from process (regional only): 0
Release fraction to wastewater from process: 1e-005
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 99.4 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: >= 76.9 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is:
4600000 kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
95.5 %
Conditions and measures related to external treatment of waste for disposal
Combustion emissions considered in regional exposure assessment [ETW2]
Combustion emissions limited by required exhaust emission controls [ETW1]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated [ERW3]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Section 1 Exposure Scenario Title
Title:
Rubber production and processing
Use Descriptor
Seite 13 von 21
Sector(s) of Use
Process Categories
SU10, SU3
PROC1, PROC15, PROC2, PROC3, PROC8a,
PROC8b, PROC9
ERC7
ESVOC 4.19.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Manufacture of tyres and general rubber articles, including processing of raw (uncured) rubber, handling and
mixing of rubber additives, vulcanising, cooling and finishing.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC2
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC2
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
Material transfers (closed systems) PROC2
Ensure material transfers are under containment or extract ventilation.
Store substance within a closed system.
Material transfers PROC8b
Ensure material transfers are under containment or extract ventilation.
Bulk weighing PROC2
Wear suitable gloves tested to EN374.
Handle substance within a closed system.
Laboratory activities PROC15
Handle in a fume cupboard or under extract ventilation.
Equipment maintenance PROC8a
Drain down system prior to equipment break-in or maintenance.
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
Store substance within a closed system.
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Seite 14 von 21
General exposures (closed systems) PROC1
Handle substance within a closed system.
General exposures (closed systems) Outdoor. PROC3
Handle substance within a closed system.
Small scale weighing PROC9
Carry out in a vented booth or extracted enclosure.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 94 tons/yr
Continuous release.
Emission Days (days/year): 20 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 1
Maximum daily site tonnage (kg/d): 4700 kg / day
Regional use tonnage (tonnes/year): 94 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.003
Release fraction to soil from process (regional only): 0.0001
Release fraction to wastewater from process: 0.01
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 0 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: >= 23.9 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Prevent discharge of undissolved substance to or recover from wastewater.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 42000
kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is =:
95.5 %
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations
[ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations
[ERW1]
Section 3 Exposure Estimation
Seite 15 von 21
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Seite 16 von 21
Section 1 Exposure Scenario Title
Title:
Use as a fuel - Professional
Use Descriptor
Sector(s) of Use
Process Categories
SU22
PROC1, PROC16, PROC2, PROC3, PROC8a,
PROC8b
ERC8B, ERC8E, ERC9A, ERC9B
ESVOC 9.12b.v1
Environmental Release Categories
Specific Environmental Release Category
Processes, tasks, activities covered
Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment
maintenance and handling of waste.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Assumes use at not more than 20°C above ambient tem perature[G15]
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures (skin irritants) PROC8b
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested
to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash
off any skin contamination immediately. provide basic employee training to prevent / minimise exposures
and to report any skin problems that may develop.
General measures (carcinogens) PROC8b
Consider technical advances and process upgrades (including automation) for the elimination of releases.
minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local
exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush
equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to operators to minimise exposures; wear suitable
gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for
certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all
control measures. Consider the need for risk based health surveillance.
Drum/batch transfers PROC8b
Ensure material transfers are under containment or extract ventilation.
General exposures (closed systems) PROC1
Handle substance within a closed system.
General exposures (closed systems) PROC2
Wear suitable gloves tested to EN374.
Handle substance within a closed system.
General exposures (closed systems) PROC3
Handle substance within a closed system.
Use as a fuel (closed systems) PROC16
Handle substance within a closed system.
refuelling PROC8b
Ensure material transfers are under containment or extract ventilation.
Equipment maintenance PROC8a
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Drain down system prior to equipment break-in or maintenance.
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Ensure operatives are trained to minimise exposures.
Wear chemically resistant gloves (tested to EN374) in combination with intensive management supervision
controls.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Clear spills immediately.
Storage PROC2
provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan.
Store substance within a closed system.
Bulk transfers (closed systems) PROC8b
Ensure material transfers are under containment or extract ventilation.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 590 tons/yr
Continuous release.
Emission Days (days/year): 365
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.0005
Maximum daily site tonnage (kg/d): 1600
Regional use tonnage (tonnes/year): 1190000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.01
Release fraction to soil from process (regional only): 1e-005
Release fraction to wastewater from process: 1e-005
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases
to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 %
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: Not Applicable
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement)
efficiency of =: >= 3.4 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 15000
kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is:
95.5 %
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Conditions and measures related to external treatment of waste for disposal
Combustion emissions considered in regional exposure assessment [ETW2]
Combustion emissions limited by required exhaust emission controls [ETW1]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated [ERW3]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone
or in combination.
Section 1 Exposure Scenario Title
Title:
Use as a fuel - Consumer
Use Descriptor
Sector(s) of Use
SU21
Product Categories
PC13
Environmental Release Categories
ERC8B
Specific Environmental Release Category
ESVOC 9.12c.v1
Processes, tasks, activities covered
Covers consumer uses in liquid fuels.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of consumer exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers concentrations up to 1 %
Covers daily use up to 1 times per day
Other given operational conditions affecting consumer exposure
Covers use at ambient temperatures.
Contributing Scenarios/Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
Liquid: Automotive Refuelling PC13
Covers annual use up to 52 days/yr
Covers skin contact area up to 210 cm2
For each use event, covers use amounts up to 37500 grams
Covers outdoor use. 0.6 Air changes per hour
Covers use in room size of 100 m³
Covers exposure up to 0.05 hour(s)
Liquid Scooter Refuelling PC13
Covers annual use up to 52 days/yr
Covers skin contact area up to 210 cm2
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For each use event, covers use amounts up to 3750 grams
Covers outdoor use. 0.6 Air changes per hour
Covers use in room size of 100 m³
Covers exposure up to 0.03 hour(s)
Liquid, Garden Equipment - Use PC13
Covers annual use up to 26 days/yr
For each use event, covers use amounts up to 750 grams
Covers outdoor use. 0.6 Air changes per hour
Covers use in room size of 100 m³
Covers exposure up to 2 hour(s)
Covers skin contact area up to 420 cm2
Liquid: Garden Equipment - Refueling PC13
Covers annual use up to 26 days/yr
Covers skin contact area up to 420 cm2
For each use event, covers use amounts up to 750 grams
Covers use in a one car garage (34 m3) under typical ventilation. 1.5 Air changes per hour
Covers use in room size of 34 m³
Covers exposure up to 0.03 hour(s)
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 7000 tons/yr
Continuous release.
Emission Days (days/year): 365 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.0005
Maximum daily site tonnage (kg/d): 19000 kg / day
Regional use tonnage (tonnes/year): 13900000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process: 0.01
Release fraction to soil from process (regional only): 1e-005
Release fraction to wastewater from process: 1e-005
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 180000
kg / day
Conditions and measures related to external treatment of waste for disposal
Combustion emissions considered in regional exposure assessment [ETW2]
Combustion emissions limited by required exhaust emission controls [ETW1]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated [ERW3]
Section 3 Exposure Estimation
3.1. Health
Not applicable
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk
model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
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4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels.[G23]
4.2. Environment
Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] 0.039321
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